Sep 26, 2019 the atsdr toxicological profile succinctly characterizes the toxicologic and adverse health effects information for the hazardous substance described here. After applying the current criteria for listing substances in the roc, the rg1 passed a motion, by a vote of 4 in favor to 3 opposed, to recommended that mtbe should be. Mtbe increases octane and oxygen levels in gasoline and reduces pollution emissions. In the unlikely event of ingestion of mtbe, appropriate lavage procedures should be considered to avoid accidental aspiration of the product. Water spray may be used t o keep fire exposed containers cool. Methyl tertbutyl ether mtbe is a flammable liquid that has been used as an additive for unleaded gasoline since the 1980s. Methanol is purchased but the isobutylene is obtained from a refinery stream. Other pertinent literature is also presented, but is described in less detail. Mtbe is a blending component of gasoline, used as an. Epa no longer updates this information, but it may be useful as a reference or resource.
Special protective actions for firefighters notify medical personnel of contaminated situations and have them take appropriate protective measures. Identification of substance mixture and of supplier product identifier. In the event of a fire, wear full protective clothing and nioshapproved selfcontained breathing apparatus with full face piece operated in the pressure demand or oth er positive pressure mode. Find product specific information including cas, msds, protocols and references. Toxic by inhalation, in contact w ith skin and if swallowed. Methyl tertiarybutyl ether is commonly referred to as mtbe. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound with a structural formula ch 3 3 coch 3.
Mtbe is widely used in global markets as a gasoline oxygenate. North america southern chemical corporation 12817994416 europe helm ag 011194023750 trinidad methanol holdings trinidad limited 18686362906 chemical name cas no. Constituent of concern methyl tertiarybutyl ether mtbe aliases mtbe, methyl tertbutyl ether, 2methoxy2methyl propane, methyl 1,1dimethylethyl ether chemical formula c 5 h 12 o or ch 3 3 coch 3 cas no. Currently, mtbe is added at 11% by volume to almost. It has a minty smell, vaguely reminiscent of diethyl ether, leading to unpleasant taste and odor in water. Ef page 1 of 10 safety data sheet methyl tertbutyl ether mtbe this msds is valid for all grades that start with catalog number 357 1. Mtbe undergoes oxidative degradation in the presence of propaneoxidizing bacterial strains. Mtbe is a common component in reformulated fuels developed to reduce smog and meet the goals of the clean air act. Drinking or breathing mtbe may cause nausea, nose and throat irritation, and nervous system effects. In the past it also had limited use as a therapeutic drug for dissolving cholesterol gallbladder stones. Corporate safety 7327506000 msds environment, health, safety internet website. Methyl tertbutyl ether mtbe is a flammable liquid which is used as an additive in unleaded gasoline. Mar 03, 2011 methyl tertbutyl ether mtbe is a flammable liquid which is used as an additive in unleaded gasoline. Box 2650 tulsa, oklahoma 74101 for emergency source.
Methyl tertbutyl ether mtbe is a flammable liquid with a distinctive, disagreeable odor. Methyl tertbutyl ether an overview sciencedirect topics. The kinetic studies of heatassisted persulfate oxidation of mtbe under various parameters suggests that. Methyl tertbutyl ether mtbe wisconsin department of. The caltrans risk asssessment implementation plan 1996 was in response to executive order w796 requiring the implementation of recommendations made by the risk assessment advisory committee committee to improve the risk assessment process in all california state agencies, departments, boards and offices. It is one of a group of chemicals commonly known as. Firefighting measures extinguishing media use dry chemical, alcohol foam, all purpose afff or carbon dioxide to extinguish fire. Mtbe is a volatile, flammable, and colorless liquid that is sparingly soluble in water. In this regard, note that the product may contain up to 0. Mtbe safety data sheet product name conforms to regulation ec no.
Mtbe is a gasoline additive used to increase octane number that is produced from methanol and isobutylene. Although hydrolysis in the presence of strong acids has been recognized as a mechanism for mtbe transformation, it has been discounted as a significant reaction under. Keep away from heat, hot surfaces, sparks, open flames and other. High purity mtbe is used as a solvent in the pharmaceutical industry and as a lab solvent. Sigmaaldrich offers supelco48027, methyl tertbutyl ether mtbe with density 0. Do not allow contact with soil, surface or ground water. Mtbe and the requirements for underground storage tank. Box 2650 tulsa, oklahoma 74101 for emergency source information contact.
Because of concerns for groundwater contamination and water quality, mtbe is now banned or limited in several states. Specific hazards arising from the chemical not available c. Material safety data sheet gasoline, all grades msds no. Mtbe production material balance project you manage a chemical plant within a refinery complex that produces 60,000 tonney of methyl tertiarybutyl ether mtbe. Pdf insitu chemical oxidation of mtbe researchgate.
Mtbe methyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. Groundwater information sheet methyl tertiarybutyl ether mtbe. Methyl tertbutyl ether safety data sheet according to federal register vol. Material can release vapors that readily form flamma ble mixtures. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Methyl tertiary butyl ether mtbe is a volatile organic compound voc commonly used as a gasoline additive.
Section 1 chemical product and company identification msds name. Mtbe has been produced in very large quantities for use as a gasoline additive since about 1979. Water spray, dry chemical, alcohol foam, or carbon dioxide. Several isco processes have been tested successfully. Methyl tbutyl ether mtbe methyl tbutyl ether mtbe is a clear, colorless organic liquid compound.
Coch find msds or sds, a coa, data sheets and more information. Mtbe is produced in very large quantities over 200,000 barrels per day in the u. This is a comprehensive list of frequently asked questions and links to other sites. Chemical product and company information hess corporation 1 hess plaza woodbridge, nj 070950961 emergency telephone number 24 hrs. Chemtrec 800 4249300 company contact business hours. Health effects of exposure to methyl tertiary butyl ether. Dry chemical, carbon dioxide, regular foam extinguishing agent, spray avoid use of water jet for extinguishing b.
Mtbe is also used as a chemical intermediate to produce high purity isobutylene. Methyl tbutyl ether, mtbe, tertbutyl methyl ether, 2methoxy2methylpropane chemical reference number cas. This lack of reactivity has led to concerns of the longterm impacts of mtbe in groundwater. The 1977 clean air act amendments set requirements for substantially similar gasoline, which requires that oxygenates be approved by the u. Subsequent revisions to california state legislation has seen the phaseout of mtbe, and a tightening of construction and. Methyl tertbutyl ether recommended use laboratory chemicals. Groundwater information sheet methyl tertiarybutyl. Chemtrec 8004249300 company contact business hours. Vapor accumulation could flash andor explode if ignited. It is made from blending chemicals such as isobutylene and methanol, and has been used since the 1980s as an additive for unleaded gasolines to achieve more efficient burning. Methyl tertbutyl ether mtbe is manufactured by the chemical reaction of methanol and isobutene for primary use in gasoline 59. Apr98 amerada hess corporation 1 hess plaza woodbridge, nj 070950961 emergency telephone number 24 hrs. Methyl tertiary butyl ether mtbe is used as a highoctane additive component that helps gasoline burn cleaner and reduces automobile emissions. The chemical abstracts service cas registry number for mtbe is 1634044.
Material safety data sheet gasoline, all grades msds. Material safety data sheet methyl tertbutyl ether mtbe msds no. Cas 1634044, ec number 2166531, chemical formula ch. The kinetic studies of heatassisted persulfate oxidation of mtbe under various parameters suggests that the reaction follows the pseudofirstorder kinetics. Unlike ethanol, mtbe does not increases evaporative emissions from gasoline and is fully fungible in existing gasoline distribution systems. Mtbe has been found in at least 11 of the 1,430 national priorities list sites identified by the environmental protection agency epa.
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